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Development of a photochemical source for the production and calibration of acyl peroxynitrate compounds
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2015
Source: Atmospheric Measurement Techniques, 8(5), 2225-2231.
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Journal Title:Atmospheric Measurement Techniques
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NOAA Program & Office:
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Description:A dynamic system for the calibration of acyl peroxynitrate compounds (APNs) has been developed in the laboratory to reduce the difficulty, required time, and instability of laboratory-produced standards for difficult-to-synthesize APN species. In this work we present a photochemical source for the generation of APN standards: acetyl peroxynitrate (PAN), propionyl peroxynitrate (PPN), acryloyl peroxynitrate (APAN), methacryloyl peroxynitrate (MPAN), and crotonyl peroxynitrate (CPAN). APNs are generated via photolysis of a mixture of acyl chloride (RC(O)Cl) and ketone (RC(= O)R) precursor compounds in the presence of O-2 and NO2. Subsequent separation by a prep-scale gas chromatograph and detection with a total NOy instrument serve to quantify the output of the APN source. Validation of the APN products was performed using iodide ion chemical ionization mass spectroscopy (I- CIMS). This method of standard production is an efficient and accurate technique for the calibration of instrumentation used to measure PAN, PPN, APAN, MPAN, and CPAN.
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Source:Atmospheric Measurement Techniques, 8(5), 2225-2231.
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Rights Information:CC BY
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Compliance:Submitted
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Main Document Checksum:urn:sha256:b2daae2decc05654177c0624c02d47be5037e7948b61c1d8f837f43b364071d5
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