i
Aqueous phase oxidation of sulphur dioxide by ozone in cloud droplets
-
2016
Source: Atmospheric Chemistry and Physics, 16(3), 1693-1712.
Details:
-
Journal Title:Atmospheric Chemistry and Physics
-
Personal Author:Hoyle, C. R. ; Fuchs, C. ; Jarvinen, E. ; Saathoff, H. ; Dias, A. ; El Haddad, I. ; Gysel, M. ; Coburn, S. C. ; Trostl, J. ; Bernhammer, A. K. ; Bianchi, F. ; Breitenlechner, M. ; Corbin, J. C. ; Craven, J. ; Donahue, N. M. ; Duplissy, J. ; Ehrhart, S. ; Frege, C. ; Gordon, H. ; Hoppel, N. ; Heinritzi, M. ; Kristensen, T. B. ; Molteni, U. ; Nichman, L. ; Pinterich, T. ; Prevot, A. S. H. ; Simon, M. ; Slowik, J. G. ; Steiner, G. ; Tome, A. ; Vogel, A. L. ; Volkamer, R. ; Wagner, A. C. ; Wagner, R. ; Wexler, A. S. ; Williamson, C. ; Winkler, P. M. ; Yan, C. ; Amorim, A. ; Dommen, J. ; Curtius, J. ; Gallagher, M. W. ; Flagan, R. C. ; Hansel, A. ; Kirkby, J. ; Kulmala, M. ; Mohler, O. ; Stratmann, F. ; Worsnop, D. R. ; Baltensperger, U. ; Less -
-
NOAA Program & Office:
-
Description:The growth of aerosol due to the aqueous phase oxidation of sulfur dioxide by ozone was measured in laboratory-generated clouds created in the Cosmics Leaving OUtdoor Droplets (CLOUD) chamber at the European Organization for Nuclear Research (CERN). Experiments were performed at 10 and -10 degrees C, on acidic (sulfuric acid) and on partially to fully neutralised (ammonium sulfate) seed aerosol. Clouds were generated by performing an adiabatic expansion-pressurising the chamber to 220 hPa above atmospheric pressure, and then rapidly releasing the excess pressure, resulting in a cooling, condensation of water on the aerosol and a cloud lifetime of approximately 6 min. A model was developed to compare the observed aerosol growth with that predicted using oxidation rate constants previously measured in bulk solutions. The model captured the measured aerosol growth very well for experiments performed at 10 and -10 degrees C, indicating that, in contrast to some previous studies, the oxidation rates of SO2 in a dispersed aqueous system can be well represented by using accepted rate constants, based on bulk measurements. To the best of our knowledge, these are the first laboratory-based measurements of aqueous phase oxidation in a dispersed, supercooled population of droplets. The measurements are therefore important in confirming that the extrapolation of currently accepted reaction rate constants to temperatures below 0 degrees C is correct.
-
Source:Atmospheric Chemistry and Physics, 16(3), 1693-1712.
-
Document Type:
-
Rights Information:CC BY
-
Compliance:Submitted
-
Main Document Checksum:urn:sha256:715d759e1858881d350dabedf8a8fb60bd532c420dfcbb805f93fb5d240e0f7e
-
File Type:
Supporting Files
-
No Additional Files
More +
Related Documents
-
- File Format:
- RIS
- File Format:
- RIS
- File Format:
- RIS
- File Format:
- RIS
- File Format:
- RIS
- File Format:
- RIS
- File Format:
- RIS
- File Format:
- RIS
- File Format:
- RIS
- File Format:
- RIS
- File Format:
- RIS
- File Format:
- RIS
- File Format:
- RIS
- File Format:
- RIS
- File Format:
- RIS
- File Format:
- RIS
- File Format:
- RIS
- File Format:
- RIS
Building evidence around ghost gear: Global trends and analysis for sustainable solutions at scaleCitePersonal Author:Richardson, K. ; Asmutis-Silvia, R. ; ...2019 | Marine Pollution Bulletin, 138, 222-229.Description:Abandoned, lost or discarded fishing gear (ALDFG) comprises a significant amount of global marine debris, with diverse impacts to marine environments,...The role of scientific expertise in local adaptation to projected sea level riseCitePersonal Author:Hayes, A. L. ; Heery, E. C. ; ...2018 | Environmental Science & Policy, 87, 55-63.Description:Adaptation to sea level rise (SLR) is primarily taking place at the local level, with varied governments grappling with the diverse ways that SLR will...A case study comparing citizen science aurora data with global auroral boundaries derived from satellite imagery and empirical modelsCitePersonal Author:Kosar, B. C. ; MacDonald, E. A. ; ...2018 | Journal of Atmospheric and Solar-Terrestrial Physics, 177, 274-282.Description:Aurorasaurus is a citizen science project that offers a new, global data source consisting of ground-based reports of the aurora. For this case study,...History of chemically and radiatively important atmospheric gases from the Advanced Global Atmospheric Gases Experiment (AGAGE)CitePersonal Author:Prinn, R. G. ; Weiss, R. F. ; ...2018 | Earth System Science Data, 10(2), 985-1018.Description:We present the organization, instrumentation, datasets, data interpretation, modeling, and accomplishments of the multinational global atmospheric mea...Real-time measurements of secondary organic aerosol formation and aging from ambient air in an oxidation flow reactor in the Los Angeles areaCitePersonal Author:Ortega, A. M. ; Hayes, P. L. ; ...2016 | Atmospheric Chemistry and Physics, 16(11), 7411-7433.Description:Field studies in polluted areas over the last decade have observed large formation of secondary organic aerosol (SOA) that is often poorly captured by...Non-OH chemistry in oxidation flow reactors for the study of atmospheric chemistry systematically examined by modelingCitePersonal Author:Peng, Z. ; Day, D. A. ; ...2016 | Atmospheric Chemistry and Physics, 16(7), 4283-4305.Description:Oxidation flow reactors (OFRs) using low-pressure Hg lamp emission at 185 and 254 nm produce OH radicals efficiently and are widely used in atmospheri...Non-methane organic gas emissions from biomass burning: identification, quantification, and emission factors from PTR-ToF during the FIREX 2016 laboratory experimentCitePersonal Author:Koss, A. R. ; Sekimoto, K. ; ...2018 | Atmospheric Chemistry and Physics, 18(5), 3299-3319.Description:Volatile and intermediate-volatility non-methane organic gases (NMOGs) released from biomass burning were measured during laboratory-simulated wildfir...First Results From Sonification and Exploratory Citizen Science of Magnetospheric ULF Waves: Long-Lasting Decreasing-Frequency Poloidal Field Line Resonance Following Geomagnetic StormsCitePersonal Author:Archer, M. O. ; Hartinger, M. D. ; ...2018 | Space Weather-the International Journal of Research and Applications, 16(11), 1753-1769.Description:Magnetospheric ultralow-frequency (ULF) waves contribute to space weather in the solar wind-magnetosphere-ionosphere system. The monitoring of these w...Atmospheric CO2 Observations Reveal Strong Correlation Between Regional Net Biospheric Carbon Uptake and Solar-Induced Chlorophyll FluorescenceCitePersonal Author:Shiga, Y. P. ; Tadic, J. M. ; ...2018 | Geophysical Research Letters, 45(2), 1122-1132.Description:Recent studies have shown the promise of remotely sensed solar-induced chlorophyll fluorescence (SIF) in informing terrestrial carbon exchange, but an...A new formulation for rotor equivalent wind speed for wind resource assessment and wind power forecastingCitePersonal Author:Choukulkar, A. ; Pichugina, Y. ; ...2016 | Wind Energy, 19(8), 1439-1452.Description:The spurt of growth in the wind energy industry has led to the development of many new technologies to study this energy resource and improve the effi...Aerial Observations of Symmetric Instability at the North Wall of the Gulf StreamCitePersonal Author:Savelyev, I. ; Thomas, L. N. ; ...2018 | Geophysical Research Letters, 45(1), 236-244.Description:An unusual spatial pattern on the ocean surface was captured by thermal airborne swaths taken across a strong sea surface temperature front at the Nor...Strong Contrast in Remote Black Carbon Aerosol Loadings Between the Atlantic and Pacific BasinsCitePersonal Author:Katich, J. M. ; Samset, B. H. ; ...2018 | Journal of Geophysical Research-Atmospheres, 123(23), 13386-13395.Description:Measurements of black carbon (BC) aerosol mass concentration in remote air are sparse, leading to poorly constrained regions that models struggle to r...The International Satellite Cloud Climatology Project H-Series climate data record productCitePersonal Author:Young, A. H. ; Knapp, K. R. ; ...2018 | Earth System Science Data, 10(1), 583-593.Description:This paper describes the new global long-term International Satellite Cloud Climatology Project (ISCCP) H-series climate data record (CDR). The H-seri...VOC species and emission inventory from vehicles and their SOA formation potentials estimation in Shanghai, ChinaCitePersonal Author:Huang, C. ; Wang, H. L. ; ...2015 | Atmospheric Chemistry and Physics, 15(19), 11081-11096.Description:Volatile organic compound (VOC) species from vehicle exhausts and gas evaporation were investigated by chassis dynamometer and on-road measurements of...Explicit Convection and Scale-Aware Cumulus Parameterizations: High-Resolution Simulations over Areas of Different Topography in GermanyCitePersonal Author:Wagner, A. ; Heinzeller, D. ; ...2018 | Monthly Weather Review, 146(6), 1925-1944.Description:An increase in the spatial resolution of regional climate model simulations improves the representation of land surface characteristics and may allow ...Personal Author:Waugh, D. W. ; Grise, K. M. ; ...2018 | Journal of Climate, 31(18), 7565-7581.Description:There is mounting evidence that the width of the tropics has increased over the last few decades, but there are large differences in reported expansio...Source Partitioning of Methane Emissions and its Seasonality in the US MidwestCitePersonal Author:Chen, Z. C. ; Griffis, T. J. ; ...2018 | Journal of Geophysical Research-Biogeosciences, 123(2), 646-659.Description:The methane (CH4) budget and its source partitioning are poorly constrained in the Midwestern United States. We used tall tower (185m) aerodynamic flu...Personal Author:Mattila, J. M. ; Brophy, P. ; ...2018 | Atmospheric Chemistry and Physics, 18(16), 12315-12327.Description:We measured organic and inorganic gas-phase acids in the Front Range of Colorado to better understand their tropospheric sources and sinks using a hig...Emissions of nitrogen-containing organic compounds from the burning of herbaceous and arboraceous biomass: Fuel composition dependence and the variability of commonly used nitrile tracersCitePersonal Author:Coggon, M. M. ; Veres, P. R. ; ...2016 | Geophysical Research Letters, 43(18), 9903-9912.Description:Volatile organic compounds (VOCs) emitted from residential wood and crop residue burning were measured in Colorado, U.S. When compared to the emission...Thermodynamic and Dynamic Causes of Pluvial Conditions During the Last Glacial Maximum in Western North AmericaCitePersonal Author:Morrill, C. ; Lowry, D. P. ; ...2018 | Geophysical Research Letters, 45(1), 335-345.Description:During the last glacial period, precipitation minus evaporation increased across the currently arid western United States. These pluvial conditions ha...
More +
You May Also Like
- File Format:
- RIS
Rates of Wintertime Atmospheric SO2 Oxidation based on Aircraft Observations during Clear-Sky Conditions over the Eastern United States
Cite
Personal Author:
Green, J. R. ; Fiddler, M. N. ; ...
2019 | Journal of Geophysical Research: Atmospheres
Description:
Sulfur dioxide (SO2) is emitted in large quantities from coal-burning power plants and leads to various harmful health and environmental effects. In t...