Welcome to the NOAA Institutional Repository |
Stacks Logo
Advanced Search
Select up to three search categories and corresponding keywords using the fields to the right. Refer to the Help section for more detailed instructions.
 
 
Help
Clear All Simple Search
Advanced Search
Non-methane organic gas emissions from biomass burning: identification, quantification, and emission factors from PTR-ToF during the FIREX 2016 laboratory experiment
  • Published Date:
    2018
  • Source:
    Atmospheric Chemistry and Physics, 18(5), 3299-3319.
Filetype[PDF-7.57 MB]


This document cannot be previewed automatically as it exceeds 5 MB
Please click the thumbnail image to view the document.
Non-methane organic gas emissions from biomass burning: identification, quantification, and emission factors from PTR-ToF during the FIREX 2016 laboratory experiment
Details:
  • Personal Author:
  • Description:
    Volatile and intermediate-volatility non-methane organic gases (NMOGs) released from biomass burning were measured during laboratory-simulated wildfires by protontransfer-reaction time-of-flight mass spectrometry (PTRToF). We identified NMOG contributors to more than 150 PTR ion masses using gas chromatography ( GC) preseparation with electron ionization, H3O+ chemical ionization, and NO+ chemical ionization, an extensive literature review, and time series correlation, providing higher certainty for ion identifications than has been previously available. Our interpretation of the PTR-ToF mass spectrum accounts for nearly 90% of NMOG mass detected by PTR-ToF across all fuel types. The relative contributions of different NMOGs to individual exact ion masses are mostly similar across many fires and fuel types. The PTR-ToF measurements are compared to corresponding measurements from open-path Fourier transform infrared spectroscopy (OP-FTIR), broadband cavity-enhanced spectroscopy (ACES), and iodide ion chemical ionization mass spectrometry (I- CIMS) where possible. The majority of comparisons have slopes near 1 and values of the linear correlation coefficient, R-2, of > 0.8, including compounds that are not frequently reported by PTR-MS such as ammonia, hydrogen cyanide (HCN), nitrous acid (HONO), and propene. The exceptions include methylglyoxal and compounds that are known to be difficult to measure with one or more of the deployed instruments. The fire-integrated emission ratios to CO and emission factors of NMOGs from 18 fuel types are provided. Finally, we provide an overview of the chemical characteristics of detected species. Non-aromatic oxygenated compounds are the most abundant. Furans and aromatics, while less abundant, comprise a large portion of the OH reactivity. The OH reactivity, its major contributors, and the volatility distribution of emissions can change considerably over the course of a fire.
  • DOI:
    http://dx.doi.org/10.5194/acp-18-3299-2018
  • Document Type:
    Journal Article
  • Funding:
    Grant no. NA16OAR4310100
  • Collection(s):
    NOAA Cooperative Institutes
    Office of Oceanic and Atmospheric Research (OAR)
  • Main Document Checksum:
  • Supporting Files:
    No Additional Files
    1. Building evidence around ghost gear: Global trends and analysis for sustainable solutions at scale
      Personal Author:
      Richardson, K.; Asmutis-Silvia, R.; Drinkwin, J.; Gilardi, K. V. K.; Giskes, I.; Jones, G.; O'Brien, K.; Pragnell-Raasch, H.; Ludwig, L.; Antonelis, K.; Barco, S.; Henry, A.; Knowlton, A.; Landry, S.; Mattila, D.; MacDonald, K.; Moore, M.; Morgan, J.; Robbins, J.; van der Hoop, J.; Hogan, E.;
      Published Date:
      2019
      Source:
      Marine Pollution Bulletin, 138, 222-229.
      Description:
      Abandoned, lost or discarded fishing gear (ALDFG) comprises a significant amount of global marine debris, with diverse impacts to marine environments, wildlife, and the fishing industry. Building evidence on ALDFG is critical to holistically understa...
      File Type:
      Filetype[PDF - 1.13 MB]
    2. The viability of trajectory analysis for diagnosing dynamical and chemical influences on ozone concentrations in the UTLS
      Personal Author:
      Bergman, J. W.; Pfister, L.; Kinnison, D. E.; Hintsa, E. J.; Thornberry, T. D.;
      Published Date:
      2017
      Source:
      Journal of Geophysical Research-Atmospheres, 122(11), 6025-6042.
      Description:
      To evaluate the utility of trajectory analysis in the tropical upper troposphere/lower stratosphere, Lagrangian predictions of ozone mixing ratio are compared to observations from the Airborne Tropical TRopopause EXperiment. Model predictions are bas...
      File Type:
      Filetype[PDF - 2.64 MB]
    3. Brown carbon aerosol in the North American continental troposphere: sources, abundance, and radiative forcing
      Personal Author:
      Liu, J.; Scheuer, E.; Dibb, J.; Diskin, G. S.; Ziemba, L. D.; Thornhill, K. L.; Anderson, B. E.; Wisthaler, A.; Mikoviny, T.; Devi, J. J.; Bergin, M.; Perring, A. E.; Markovic, M. Z.; Schwarz, J. P.; Campuzano-Jost, P.; Day, D. A.; Jimenez, J. L.; Weber, R. J.;
      Published Date:
      2015
      Source:
      Atmospheric Chemistry and Physics, 15(14), 7841-7858.
      Description:
      Chemical components of organic aerosol (OA) selectively absorb light at short wavelengths. In this study, the prevalence, sources, and optical importance of this so-called brown carbon (BrC) aerosol component are investigated throughout the North Ame...
      File Type:
      Filetype[PDF - 416.94 KB]
    4. Weakening of the weekend ozone effect over California's South Coast Air Basin
      Personal Author:
      Baidar, S.; Hardesty, R. M.; Kim, S. W.; Langford, A. O.; Oetjen, H.; Senff, C. J.; Trainer, M.; Volkamer, R.;
      Published Date:
      2015
      Source:
      Geophysical Research Letters, 42(21), 9457-9464.
      Description:
      We have observed lower nitrogen dioxide (NO2) and ozone (O-3) during a hot weekend (summer 2010) from aircraft over the entire South Coast Air Basin (SoCAB). Surface concentrations of NO2, O-3, and temperature from 1996 to 2014 corroborate that this ...
      File Type:
      Filetype[PDF - 936.36 KB]
    5. An atmospheric photochemical source of the persistent greenhouse gas CF4
      Personal Author:
      Jubb, A. M.; McGillen, M. R.; Portmann, R. W.; Daniel, J. S.; Burkholder, J. B.;
      Published Date:
      2015
      Source:
      Geophysical Research Letters, 42(21), 9505-9511.
      Description:
      A previously uncharacterized atmospheric source of the persistent greenhouse gas tetrafluoromethane, CF4, has been identified in the UV photolysis of trifluoroacetyl fluoride, CF3C(O)F, which is a degradation product of several halocarbons currently ...
      File Type:
      Filetype[PDF - 356.96 KB]
    6. Modeling the formation and aging of secondary organic aerosols in Los Angeles during CalNex 2010
      Personal Author:
      Hayes, P. L.; Carlton, A. G.; Baker, K. R.; Ahmadov, R.; Washenfelder, R. A.; Alvarez, S.; Rappengluck, B.; Gilman, J. B.; Kuster, W. C.; de Gouw, J. A.; Zotter, P.; Prevot, A. S. H.; Szidat, S.; Kleindienst, T. E.; Offenberg, J. H.; Ma, P. K.; Jimenez, J. L.;
      Published Date:
      2015
      Source:
      Atmospheric Chemistry and Physics, 15(10), 5773-5801.
      Description:
      Four different literature parameterizations for the formation and evolution of urban secondary organic aerosol (SOA) frequently used in 3-D models are evaluated using a 0-D box model representing the Los Angeles metropolitan region during the Califor...
      File Type:
      Filetype[PDF - 952.55 KB]
    7. Origins of aerosol chlorine during winter over north central Colorado, USA
      Personal Author:
      Jordan, C. E.; Pszenny, A. A. P.; Keene, W. C.; Cooper, O. R.; Deegan, B.; Maben, J.; Routhier, M.; Sander, R.; Young, A. H.;
      Published Date:
      2015
      Source:
      Journal of Geophysical Research-Atmospheres, 120(2), 678-694.
      Description:
      The Nitrogen, Aerosol Composition, and Halogens on a Tall Tower campaign (February-March 2011) near Boulder, Colorado, investigated nighttime ClNO2 production and processing. Virtually all particulate Cl was in the form of ionic Cl-. The size distrib...
      File Type:
      Filetype[PDF - 1.42 MB]
    8. The impact of current CH4 and N2O atmospheric loss process uncertainties on calculated ozone abundances and trends
      Personal Author:
      Fleming, E. L.; George, C.; Heard, D. E.; Jackman, C. H.; Kurylo, M. J.; Mellouki, W.; Orkin, V. L.; Swartz, W. H.; Wallington, T. J.; Wine, P. H.; Burkholder, J. B.;
      Published Date:
      2015
      Source:
      Journal of Geophysical Research-Atmospheres, 120(10), 5267-5293.
      Description:
      The atmospheric loss processes of N2O and CH4, their estimated uncertainties, lifetimes, and impacts on ozone abundance and long-term trends are examined using atmospheric model calculations and updated kinetic and photochemical parameters and uncert...
      File Type:
      Filetype[PDF - 6.81 MB]
    9. Validation of TES ammonia observations at the single pixel scale in the San Joaquin Valley during DISCOVER-AQ
      Personal Author:
      Sun, K.; Cady-Pereira, K.; Miller, D. J.; Tao, L.; Zondlo, M. A.; Nowak, J. B.; Neuman, J. A.; Mikoviny, T.; Muller, M.; Wisthaler, A.; Scarino, A. J.; Hostetler, C. A.;
      Published Date:
      2015
      Source:
      Journal of Geophysical Research-Atmospheres, 120(10), 5140-5154.
      Description:
      Ammonia measurements from a vehicle-based, mobile open-path sensor and those from aircraft were compared with Tropospheric Emission Spectrometer (TES) NH3 columns at the pixel scale during the NASA Deriving Information on Surface conditions from Colu...
      File Type:
      Filetype[PDF - 4.13 MB]
    10. A two-channel, tunable diode laser-based hygrometer for measurement of water vapor and cirrus cloud ice water content in the upper troposphere and lower stratosphere
      Personal Author:
      Thornberry, T. D.; Rollins, A. W.; Gao, R. S.; Watts, L. A.; Ciciora, S. J.; McLaughlin, R. J.; Fahey, D. W.;
      Published Date:
      2015
      Source:
      Atmospheric Measurement Techniques, 8(1), 211-224.
      Description:
      The recently developed NOAA Water instrument is a two-channel, closed-path, tunable diode laser absorption spectrometer designed for the measurement of upper troposphere/lower stratosphere water vapor and enhanced total water (vapor + inertially enha...
      File Type:
      Filetype[PDF - 2.65 MB]
    11. Improving a global model from the boundary layer: Total turbulent energy and the neutral limit Prandtl number
      Personal Author:
      Pithan, F.; Angevine, W.; Mauritsen, T.;
      Published Date:
      2015
      Source:
      Journal of Advances in Modeling Earth Systems, 7(2), 791-805.
      Description:
      Model intercomparisons have identified important deficits in the representation of the stable boundary layer by turbulence parametrizations used in current weather and climate models. However, detrimental impacts of more realistic schemes on the larg...
      File Type:
      Filetype[PDF - 2.79 MB]
    12. Compiled records of carbon isotopes in atmospheric CO2 for historical simulations in CMIP6
      Personal Author:
      Graven, H.; Allison, C. E.; Etheridge, D. M.; Hammer, S.; Keeling, R. F.; Levin, I.; Meijer, H. A. J.; Rubino, M.; Tans, P. P.; Trudinger, C. M.; Vaughn, B. H.; White, J. W. C.;
      Published Date:
      2017
      Source:
      Geoscientific Model Development, 10(12), 4405-4417.
      Description:
      The isotopic composition of carbon (Delta C-14 and delta C-13) in atmospheric CO2 and in oceanic and terrestrial carbon reservoirs is influenced by anthropogenic emissions and by natural carbon exchanges, which can respond to and drive changes in cli...
      File Type:
      Filetype[PDF - 3.29 MB]
    13. Observation of isoprene hydroxynitrates in the southeastern United States and implications for the fate of NOx
      Personal Author:
      Xiong, F.; McAvey, K. M.; Pratt, K. A.; Groff, C. J.; Hostetler, M. A.; Lipton, M. A.; Starn, T. K.; Seeley, J. V.; Bertman, S. B.; Teng, A. P.; Crounse, J. D.; Nguyen, T. B.; Wennberg, P. O.; Misztal, P. K.; Goldstein, A. H.; Guenther, A. B.; Koss, A. R.; Olson, K. F.; de Gouw, J. A.; Baumann, K.; Edgerton, E. S.; Feiner, P. A.; Zhang, L.; Miller, D. O.; Brune, W. H.; Shepson, P. B.;
      Published Date:
      2015
      Source:
      Atmospheric Chemistry and Physics, 15(19), 11257-11272.
      Description:
      Isoprene hydroxynitrates (IN) are tracers of the photochemical oxidation of isoprene in high NOx environments. Production and loss of IN have a significant influence on the NOx cycle and tropospheric O-3 chemistry. To better understand IN chemistry, ...
      File Type:
      Filetype[PDF - 698.09 KB]
    14. VOC species and emission inventory from vehicles and their SOA formation potentials estimation in Shanghai, China
      Personal Author:
      Huang, C.; Wang, H. L.; Li, L.; Wang, Q.; Lu, Q.; de Gouw, J. A.; Zhou, M.; Jing, S. A.; Lu, J.; Chen, C. H.;
      Published Date:
      2015
      Source:
      Atmospheric Chemistry and Physics, 15(19), 11081-11096.
      Description:
      Volatile organic compound (VOC) species from vehicle exhausts and gas evaporation were investigated by chassis dynamometer and on-road measurements of nine gasoline vehicles, seven diesel vehicles, five motorcycles, and four gas evaporation samples. ...
      File Type:
      Filetype[PDF - 1.18 MB]
    15. Particulate organic nitrates observed in an oil and natural gas production region during wintertime
      Personal Author:
      Lee, L.; Wooldridge, P. J.; deGouw, J.; Brown, S. S.; Bates, T. S.; Quinn, P. K.; Cohen, R. C.;
      Published Date:
      2015
      Source:
      Atmospheric Chemistry and Physics, 15(16), 9313-9325.
      Description:
      Organic nitrates in both gas and condensed (aerosol) phases were measured during the Uintah Basin Winter Ozone Study from January to February in 2012. A high degree of correlation between total aerosol volume at diameters less than 500 nm and the par...
      File Type:
      Filetype[PDF - 1.29 MB]
    16. On the reversibility of transitions between closed and open cellular convection
      Personal Author:
      Feingold, G.; Koren, I.; Yamaguchi, T.; Kazil, J.;
      Published Date:
      2015
      Source:
      Atmospheric Chemistry and Physics, 15(13), 7351-7367.
      Description:
      The two-way transition between closed and open cellular convection is addressed in an idealized cloud-resolving modeling framework. A series of cloud-resolving simulations shows that the transition between closed and open cellular states is asymmetri...
      File Type:
      Filetype[PDF - 5.79 MB]
    17. Measurements of light-absorbing particles on the glaciers in the Cordillera Blanca, Peru
      Personal Author:
      Schmitt, C. G.; All, J. D.; Schwarz, J. P.; Arnott, W. P.; Cole, R. J.; Lapham, E.; Celestian, A.;
      Published Date:
      2015
      Source:
      Cryosphere, 9(1), 331-340.
      Description:
      Glaciers in the tropical Andes have been rapidly losing mass since the 1970s. In addition to the documented increase in temperature, increases in light-absorbing particles deposited on glaciers could be contributing to the observed glacier loss. Here...
      File Type:
      Filetype[PDF - 2.37 MB]
    18. HTAP_v2.2: a mosaic of regional and global emission grid maps for 2008 and 2010 to study hemispheric transport of air pollution
      Personal Author:
      Janssens-Maenhout, G.; Crippa, M.; Guizzardi, D.; Dentener, F.; Muntean, M.; Pouliot, G.; Keating, T.; Zhang, Q.; Kurokawa, J.; Wankmuller, R.; van der Gon, H. D.; Kuenen, J. J. P.; Klimont, Z.; Frost, G.; Darras, S.; Koffi, B.; Li, M.;
      Published Date:
      2015
      Source:
      Atmospheric Chemistry and Physics, 15(19), 11411-11432.
      Description:
      The mandate of the Task Force Hemispheric Transport of Air Pollution (TF HTAP) under the Convention on Long-Range Transboundary Air Pollution (CLRTAP) is to improve the scientific understanding of the intercontinental air pollution transport, to quan...
      File Type:
      Filetype[PDF - 3.54 MB]
    19. Aqueous-phase oligomerization of methyl vinyl ketone through photooxidation - Part 2: Development of the chemical mechanism and atmospheric implications
      Personal Author:
      Ervens, B.; Renard, P.; Tlili, S.; Ravier, S.; Clement, J. L.; Monod, A.;
      Published Date:
      2015
      Source:
      Atmospheric Chemistry and Physics, 15(16), 9109-9127.
      Description:
      Laboratory experiments of efficient oligomerization from methyl vinyl ketone (MVK) in the bulk aqueous phase were simulated in a box model. Kinetic data are applied (if known) or fitted to the observed MVK decay and oligomer mass increase. Upon model...
      File Type:
      Filetype[PDF - 1.93 MB]
    20. Towards validation of ammonia (NH3) measurements from the IASI satellite
      Personal Author:
      Van Damme, M.; Clarisse, L.; Dammers, E.; Liu, X.; Nowak, J. B.; Clerbaux, C.; Flechard, C. R.; Galy-Lacaux, C.; Xu, W.; Neuman, J. A.; Tang, Y. S.; Sutton, M. A.; Erisman, J. W.; Coheur, P. F.;
      Published Date:
      2015
      Source:
      Atmospheric Measurement Techniques, 8(3), 1575-1591.
      Description:
      Limited availability of ammonia (NH3) observations is currently a barrier for effective monitoring of the nitrogen cycle. It prevents a full understanding of the atmospheric processes in which this trace gas is involved and therefore impedes determin...
      File Type:
      Filetype[PDF - 4.36 MB]
You May Also Like:
  1. Search Terms - Coupled - 05/2020
    Published Date:
    05/2020
    Series:
    Search Terms - Coupled
    File Type:
    Filetype[CSV - 2.79 MB]
  2. Collection Updates - 05/2020
    Published Date:
    05/2020
    Series:
    Collection Updates
    File Type:
    Filetype[EXCEL - 29.00 KB]