Emissions of nitrogen-containing organic compounds from the burning of herbaceous and arboraceous biomass: Fuel composition dependence and the variability of commonly used nitrile tracers
Volatile organic compounds (VOCs) emitted from residential wood and crop residue burning were measured in Colorado, U.S. When compared to the emissions from crop burning, residential wood burning exhibited markedly lower concentrations of acetonitrile, a commonly used biomass burning tracer. For both herbaceous and arboraceous fuels, the emissions of nitrogen-containing VOCs (NVOCs) strongly depend on the fuel nitrogen content; therefore, low NVOC emissions from residential wood burning result from the combustion of low-nitrogen fuel. Consequently, the emissions of compounds hazardous to human health, such as HNCO and HCN, and the formation of secondary pollutants, such as ozone generated by NOx, are likely to depend on fuel nitrogen. These results also demonstrate that acetonitrile may not be a suitable tracer for domestic burning in urban areas. Wood burning emissions may be best identified through analysis of the emissions profile rather than reliance on a single tracer species.
Liu, J.; Scheuer, E.; Dibb, J.; Diskin, G. S.; Ziemba, L. D.; Thornhill, K. L.; Anderson, B. E.; Wisthaler, A.; Mikoviny, T.; Devi, J. J.; Bergin, M.; Perring, A. E.; Markovic, M. Z.; Schwarz, J. P.; Campuzano-Jost, P.; Day, D. A.; Jimenez, J. L.; Weber, R. J.;
Published Date:
2015
Source:
Atmospheric Chemistry and Physics, 15(14), 7841-7858.
Description:
Chemical components of organic aerosol (OA) selectively absorb light at short wavelengths. In this study, the prevalence, sources, and optical importance of this so-called brown carbon (BrC) aerosol component are investigated throughout the North Ame...
Baidar, S.; Hardesty, R. M.; Kim, S. W.; Langford, A. O.; Oetjen, H.; Senff, C. J.; Trainer, M.; Volkamer, R.;
Published Date:
2015
Source:
Geophysical Research Letters, 42(21), 9457-9464.
Description:
We have observed lower nitrogen dioxide (NO2) and ozone (O-3) during a hot weekend (summer 2010) from aircraft over the entire South Coast Air Basin (SoCAB). Surface concentrations of NO2, O-3, and temperature from 1996 to 2014 corroborate that this ...
Jubb, A. M.; McGillen, M. R.; Portmann, R. W.; Daniel, J. S.; Burkholder, J. B.;
Published Date:
2015
Source:
Geophysical Research Letters, 42(21), 9505-9511.
Description:
A previously uncharacterized atmospheric source of the persistent greenhouse gas tetrafluoromethane, CF4, has been identified in the UV photolysis of trifluoroacetyl fluoride, CF3C(O)F, which is a degradation product of several halocarbons currently ...
Hayes, P. L.; Carlton, A. G.; Baker, K. R.; Ahmadov, R.; Washenfelder, R. A.; Alvarez, S.; Rappengluck, B.; Gilman, J. B.; Kuster, W. C.; de Gouw, J. A.; Zotter, P.; Prevot, A. S. H.; Szidat, S.; Kleindienst, T. E.; Offenberg, J. H.; Ma, P. K.; Jimenez, J. L.;
Published Date:
2015
Source:
Atmospheric Chemistry and Physics, 15(10), 5773-5801.
Description:
Four different literature parameterizations for the formation and evolution of urban secondary organic aerosol (SOA) frequently used in 3-D models are evaluated using a 0-D box model representing the Los Angeles metropolitan region during the Califor...
Jordan, C. E.; Pszenny, A. A. P.; Keene, W. C.; Cooper, O. R.; Deegan, B.; Maben, J.; Routhier, M.; Sander, R.; Young, A. H.;
Published Date:
2015
Source:
Journal of Geophysical Research-Atmospheres, 120(2), 678-694.
Description:
The Nitrogen, Aerosol Composition, and Halogens on a Tall Tower campaign (February-March 2011) near Boulder, Colorado, investigated nighttime ClNO2 production and processing. Virtually all particulate Cl was in the form of ionic Cl-. The size distrib...
Fleming, E. L.; George, C.; Heard, D. E.; Jackman, C. H.; Kurylo, M. J.; Mellouki, W.; Orkin, V. L.; Swartz, W. H.; Wallington, T. J.; Wine, P. H.; Burkholder, J. B.;
Published Date:
2015
Source:
Journal of Geophysical Research-Atmospheres, 120(10), 5267-5293.
Description:
The atmospheric loss processes of N2O and CH4, their estimated uncertainties, lifetimes, and impacts on ozone abundance and long-term trends are examined using atmospheric model calculations and updated kinetic and photochemical parameters and uncert...
Sun, K.; Cady-Pereira, K.; Miller, D. J.; Tao, L.; Zondlo, M. A.; Nowak, J. B.; Neuman, J. A.; Mikoviny, T.; Muller, M.; Wisthaler, A.; Scarino, A. J.; Hostetler, C. A.;
Published Date:
2015
Source:
Journal of Geophysical Research-Atmospheres, 120(10), 5140-5154.
Description:
Ammonia measurements from a vehicle-based, mobile open-path sensor and those from aircraft were compared with Tropospheric Emission Spectrometer (TES) NH3 columns at the pixel scale during the NASA Deriving Information on Surface conditions from Colu...
The recently developed NOAA Water instrument is a two-channel, closed-path, tunable diode laser absorption spectrometer designed for the measurement of upper troposphere/lower stratosphere water vapor and enhanced total water (vapor + inertially enha...
Journal of Advances in Modeling Earth Systems, 7(2), 791-805.
Description:
Model intercomparisons have identified important deficits in the representation of the stable boundary layer by turbulence parametrizations used in current weather and climate models. However, detrimental impacts of more realistic schemes on the larg...
Xiong, F.; McAvey, K. M.; Pratt, K. A.; Groff, C. J.; Hostetler, M. A.; Lipton, M. A.; Starn, T. K.; Seeley, J. V.; Bertman, S. B.; Teng, A. P.; Crounse, J. D.; Nguyen, T. B.; Wennberg, P. O.; Misztal, P. K.; Goldstein, A. H.; Guenther, A. B.; Koss, A. R.; Olson, K. F.; de Gouw, J. A.; Baumann, K.; Edgerton, E. S.; Feiner, P. A.; Zhang, L.; Miller, D. O.; Brune, W. H.; Shepson, P. B.;
Published Date:
2015
Source:
Atmospheric Chemistry and Physics, 15(19), 11257-11272.
Description:
Isoprene hydroxynitrates (IN) are tracers of the photochemical oxidation of isoprene in high NOx environments. Production and loss of IN have a significant influence on the NOx cycle and tropospheric O-3 chemistry. To better understand IN chemistry, ...
Huang, C.; Wang, H. L.; Li, L.; Wang, Q.; Lu, Q.; de Gouw, J. A.; Zhou, M.; Jing, S. A.; Lu, J.; Chen, C. H.;
Published Date:
2015
Source:
Atmospheric Chemistry and Physics, 15(19), 11081-11096.
Description:
Volatile organic compound (VOC) species from vehicle exhausts and gas evaporation were investigated by chassis dynamometer and on-road measurements of nine gasoline vehicles, seven diesel vehicles, five motorcycles, and four gas evaporation samples. ...
Lee, L.; Wooldridge, P. J.; deGouw, J.; Brown, S. S.; Bates, T. S.; Quinn, P. K.; Cohen, R. C.;
Published Date:
2015
Source:
Atmospheric Chemistry and Physics, 15(16), 9313-9325.
Description:
Organic nitrates in both gas and condensed (aerosol) phases were measured during the Uintah Basin Winter Ozone Study from January to February in 2012. A high degree of correlation between total aerosol volume at diameters less than 500 nm and the par...
Atmospheric Chemistry and Physics, 15(13), 7351-7367.
Description:
The two-way transition between closed and open cellular convection is addressed in an idealized cloud-resolving modeling framework. A series of cloud-resolving simulations shows that the transition between closed and open cellular states is asymmetri...
Schmitt, C. G.; All, J. D.; Schwarz, J. P.; Arnott, W. P.; Cole, R. J.; Lapham, E.; Celestian, A.;
Published Date:
2015
Source:
Cryosphere, 9(1), 331-340.
Description:
Glaciers in the tropical Andes have been rapidly losing mass since the 1970s. In addition to the documented increase in temperature, increases in light-absorbing particles deposited on glaciers could be contributing to the observed glacier loss. Here...
Janssens-Maenhout, G.; Crippa, M.; Guizzardi, D.; Dentener, F.; Muntean, M.; Pouliot, G.; Keating, T.; Zhang, Q.; Kurokawa, J.; Wankmuller, R.; van der Gon, H. D.; Kuenen, J. J. P.; Klimont, Z.; Frost, G.; Darras, S.; Koffi, B.; Li, M.;
Published Date:
2015
Source:
Atmospheric Chemistry and Physics, 15(19), 11411-11432.
Description:
The mandate of the Task Force Hemispheric Transport of Air Pollution (TF HTAP) under the Convention on Long-Range Transboundary Air Pollution (CLRTAP) is to improve the scientific understanding of the intercontinental air pollution transport, to quan...
Atmospheric Chemistry and Physics, 15(16), 9109-9127.
Description:
Laboratory experiments of efficient oligomerization from methyl vinyl ketone (MVK) in the bulk aqueous phase were simulated in a box model. Kinetic data are applied (if known) or fitted to the observed MVK decay and oligomer mass increase. Upon model...
Van Damme, M.; Clarisse, L.; Dammers, E.; Liu, X.; Nowak, J. B.; Clerbaux, C.; Flechard, C. R.; Galy-Lacaux, C.; Xu, W.; Neuman, J. A.; Tang, Y. S.; Sutton, M. A.; Erisman, J. W.; Coheur, P. F.;
Limited availability of ammonia (NH3) observations is currently a barrier for effective monitoring of the nitrogen cycle. It prevents a full understanding of the atmospheric processes in which this trace gas is involved and therefore impedes determin...
Fried, A.; Barth, M. C.; Bela, M.; Weibring, P.; Richter, D.; Walega, J.; Li, Y.; Pickering, K.; Apel, E.; Hornbrook, R.; Hills, A.; Riemer, D. D.; Blake, N.; Blake, D. R.; Schroeder, J. R.; Luo, Z. J.; Crawford, J. H.; Olson, J.; Rutledge, S.; Betten, D.; Biggerstaff, M. I.; Diskin, G. S.; Sachse, G.; Campos, T.; Flocke, F.; Weinheimer, A.; Cantrell, C.; Pollack, I.; Peischl, J.; Froyd, K.; Wisthaler, A.; Mikoviny, T.; Woods, S.;
Published Date:
2016
Source:
Journal of Geophysical Research-Atmospheres, 121(12), 7430-7460.
Description:
We have developed semi-independent methods for determining CH2O scavenging efficiencies (SEs) during strong midlatitude convection over the western, south-central Great Plains, and southeastern regions of the United States during the 2012 Deep Convec...
Tilmes, S.; Lamarque, J. F.; Emmons, L. K.; Kinnison, D. E.; Ma, P. L.; Liu, X.; Ghan, S.; Bardeen, C.; Arnold, S.; Deeter, M.; Vitt, F.; Ryerson, T.; Elkins, J. W.; Moore, F.; Spackman, J. R.; Martin, M. V.;
Published Date:
2015
Source:
Geoscientific Model Development, 8(5), 1395-1426.
Description:
The Community Atmosphere Model (CAM), version 5, is now coupled to extensive tropospheric and stratospheric chemistry, called CAM5-chem, and is available in addition to CAM4-chem in the Community Earth System Model (CESM) version 1.2. The main focus ...
Wagner, N. L.; Brock, C. A.; Angevine, W. M.; Beyersdorf, A.; Campuzano-Jost, P.; Day, D.; de Gouw, J. A.; Diskin, G. S.; Gordon, T. D.; Graus, M. G.; Holloway, J. S.; Huey, G.; Jimenez, J. L.; Lack, D. A.; Liao, J.; Liu, X.; Markovic, M. Z.; Middlebrook, A. M.; Mikoviny, T.; Peischl, J.; Perring, A. E.; Richardson, M. S.; Ryerson, T. B.; Schwarz, J. P.; Warneke, C.; Welti, A.; Wisthaler, A.; Ziemba, L. D.; Murphy, D. M.;
Published Date:
2015
Source:
Atmospheric Chemistry and Physics, 15(12), 7085-7102.
Description:
Vertical profiles of submicron aerosol from in situ aircraft-based measurements were used to construct aggregate profiles of chemical, microphysical, and optical properties. These vertical profiles were collected over the southeastern United States (...
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