Rate coefficients for the gas‐phase reaction of OH radicals with the L4, L5, D5, and D6 permethylsiloxanes

Details

• Journal Title:
  International Journal of Chemical Kinetics
• Personal Author:
  Bernard, François ; Burkholder, James B.
• NOAA Program & Office:
  OAR (Oceanic and Atmospheric Research) ; CIRES (Cooperative Institute for Research in Environmental Sciences) ; CSL (Chemical Sciences Laboratory)
• Description:
  Rate coefficients, k(T), for the gas‐phase OH radical reaction with decamethyltetrasiloxane ((CH3)3SiO[Si(CH3)2O]2Si(CH3)3, L4, k1), dodecamethylpentasiloxane ((CH3)3SiO[Si(CH3)2O]3Si(CH3)3, L5, k2), and decamethylcyclopentasiloxane ([–Si(CH3)2O–]5, D5, k3), and dodecamethylcyclohexasiloxane ([–Si(CH3)2O–]6, D6, k4) were measured using a pulsed laser photolysis—laser induced fluorescence absolute method over the temperature range 270–370 K.
• Source:
  International Journal of Chemical Kinetics (2024)
• DOI:
  https://doi.org/10.1002/kin.21769
• ISSN:
  0538-8066 ; 1097-4601
• Format:
  pdf
• Publisher:
  Wiley
• Document Type:
  Journal Article
• License:
  https://creativecommons.org/licenses/by-nc/4.0/
• Rights Information:
  CC BY-NC
• Compliance:
  Library
• Main Document Checksum:
  urn:sha-512:0c9f4dc6344127f0f3273894a54c448f46738ef57c72d80b8a130955d85074446bc692c5c031c40f292297138290d5527fbb9a881cfc153e6602c56561edde20
• Download URL:
  https://repository.library.noaa.gov/view/noaa/68113/noaa_68113_DS1.pdf
• File Type:
  [PDF - 1.23 MB ]