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Rate Coefficients for the Cl Atom Gas‐Phase Reaction With Permethylsiloxanes (PMS): L2, L3, L4, L5, D3, D4, D5, and D6
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2024
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Source: International Journal of Chemical Kinetics, 57(3), 213-231
[PDF-1.86 MB]
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Journal Title:International Journal of Chemical Kinetics
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Description:Rate coefficients, k(T), for the gas-phase Cl atom reaction with hexamethyldisiloxane ((CH3)3SiOSi(CH3)3, L2), k1; octamethyltrisiloxane ([(CH3)3SiO]2Si(CH3)2, L3), k2; decamethyltetrasiloxane ((CH3)3SiO[Si(CH3)2O]2Si(CH3)3, L4, k3; dodecamethylpentasiloxane ((CH3)3SiO[Si(CH3)2O]3Si(CH3)3, L5, k4; hexamethylcyclotrisiloxane ([-Si(CH3)2O-]3, D3), k5; octamethylcyclotetrasiloxane ([-Si(CH3)2O-]4, D4), k6; decamethylcyclopentasiloxane ([-Si(CH3)2O-]5, D5, k7), and dodecamethylcyclohexasiloxane ([-Si(CH3)2O-]6, D6, k8) were measured over a range of temperature (273–363 K) using a pulsed laser photolysis (PLP) – resonance fluorescence (RF) technique.
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Source:International Journal of Chemical Kinetics, 57(3), 213-231
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ISSN:0538-8066;1097-4601;
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Rights Information:CC BY-NC
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