OH reaction rate coefficients, infrared spectra, and climate metrics for (E)‐ and (Z)‐ 2‐perfluoroheptene (2‐C7F14) and 3‐perfluoroheptene (3‐C7F14)

Chattopadhyay, Aparajeo; Papadimitriou, Vassileios C.; Burkholder, James B.

doi:10.1002/kin.21643

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OH reaction rate coefficients, infrared spectra, and climate metrics for (E)‐ and (Z)‐ 2‐perfluoroheptene (2‐C7F14) and 3‐perfluoroheptene (3‐C7F14)

2023
By Chattopadhyay, Aparajeo ; Papadimitriou, Vassileios C. ; Burkholder, James B.
Source: International Journal of Chemical Kinetics, 55(7), 392-401

[PDF-1.30 MB]

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Details:

Journal Title:

International Journal of Chemical Kinetics
Personal Author:

Chattopadhyay, Aparajeo ; Papadimitriou, Vassileios C. ; Burkholder, James B.

Chattopadhyay, Aparajeo ; Papadimitriou, Vassileios C. ; Burkholder, James B. Less -
NOAA Program & Office:

OAR (Oceanic and Atmospheric Research) ; CIRES (Cooperative Institute for Research in Environmental Sciences) ; CSL (Chemical Sciences Laboratory)

OAR (Oceanic and Atmospheric Research) ; CIRES (Cooperative Institute for Research in Environmental Sciences) ; CSL (Chemical Sciences Laboratory) Less -
Description:

In this work, perfluoroheptene 2- and 3-C 7F14stereoisomer specific gas-phase OHreactionratecoefficients, k,weremeasuredat296Kin ∼600T orr(Hebath gas) using a relative rate (RR) method. Gas-chromatography (GC) with elec- tron capture detection (ECD) was used for the separation and detection of the stereoisomers.Ratecoefficientsfor( E)-2-C7F14,(Z)-2-C7F14,(E)-3-C7F14,and(Z)- 3-C7F14weremeasuredtobe(inunitsof10−13cm3molecule−1s−1)(3.60±0.51),
Keywords:

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Biochemistry Inorganic Chemistry Organic Chemistry Physical And Theoretical Chemistry
Source:

International Journal of Chemical Kinetics, 55(7), 392-401
DOI:

https://doi.org/10.1002/kin.21643
ISSN:

0538-8066;1097-4601;
Format:

PDF
Publisher:

Wiley
Document Type:

Journal Article
License:

https://creativecommons.org/publicdomain/zero/1.0/
Rights Information:

CC0 Public Domain
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Library
Main Document Checksum:

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urn:sha256:2b181ff4db707b7324b5da544d257933da32ab32aadd41269435f07043e1d7cd
Download URL:

https://repository.library.noaa.gov/view/noaa/52816/noaa_52816_DS1.pdf
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Machine readable version (XML)

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