H 2 O 2 and CH 3 OOH (MHP) in the Remote Atmosphere: 2. Physical and Chemical Controls

Allen, Hannah M.; Bates, Kelvin H.; Crounse, John D.; Kim, Michelle J.; Teng, Alexander P.; Ray, Eric A.; Wennberg, Paul O.

doi:10.1029/2021jd035702

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H 2 O 2 and CH 3 OOH (MHP) in the Remote Atmosphere: 2. Physical and Chemical Controls

2022
By Allen, Hannah M. ; Bates, Kelvin H. ; Crounse, John D. ; ...
Source: Journal of Geophysical Research: Atmospheres, 127(6)

[PDF-1.66 MB]

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Journal Title:

Journal of Geophysical Research: Atmospheres
Personal Author:

Allen, Hannah M. ; Bates, Kelvin H. ; Crounse, John D. ; Kim, Michelle J. ; Teng, Alexander P. ; ... More +

Allen, Hannah M. ; Bates, Kelvin H. ; Crounse, John D. ; Kim, Michelle J. ; Teng, Alexander P. ; Ray, Eric A. ; Wennberg, Paul O. Less -
NOAA Program & Office:

OAR (Oceanic and Atmospheric Research) ; CIRES (Cooperative Institute for Research in Environmental Sciences) ; ESRL (Earth System Research Laboratory)

OAR (Oceanic and Atmospheric Research) ; CIRES (Cooperative Institute for Research in Environmental Sciences) ; ESRL (Earth System Research Laboratory) Less -
Description:

Hydrogen peroxide (H2O2) and methyl hydroperoxide (MHP, CH3OOH) serve as HOx (OH and HO2 radicals) reservoirs and therefore as useful tracers of HOx chemistry. Both hydroperoxides were measured during the 2016–2018 Atmospheric Tomography Mission as part of a global survey of the remote troposphere over the Pacific and Atlantic Ocean basins conducted using the NASA DC-8 aircraft. To assess the relative contributions of chemical and physical processes to the global hydroperoxide budget and their impact on atmospheric oxidation potential, we compare the observations with two models, a diurnal steady-state photochemical box model and the global chemical transport model Goddard Earth Observing System (GEOS)-
Keywords:

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Atmospheric Science Earth And Planetary Sciences (miscellaneous) Geophysics Space And Planetary Science
Source:

Journal of Geophysical Research: Atmospheres, 127(6)
DOI:

https://doi.org/10.1029/2021jd035702
ISSN:

2169-897X;2169-8996;
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PDF
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American Geophysical Union (AGU)
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Journal Article
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urn:sha256:d4466cb0ec8c1151a8af0be7f2588e7c330a5d43bc225362095830ad733eb5e1
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https://repository.library.noaa.gov/view/noaa/52460/noaa_52460_DS1.pdf
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