Detection and variability of combustion-derived vapor in an urban basin
Advanced Search
Select up to three search categories and corresponding keywords using the fields to the right. Refer to the Help section for more detailed instructions.
 
 
i


Detection and variability of combustion-derived vapor in an urban basin
  • Published Date:

    2018

  • Source:
    Atmospheric Chemistry and Physics, 18, 8529–8547
Filetype[PDF-4.38 MB]


Details:
  • Description:
    Water emitted during combustion may comprise a significant portion of ambient humidity (>  10 %) in urban areas, where combustion emissions are strongly focused in space and time. Stable water vapor isotopes can be used to apportion measured humidity values between atmospherically transported and combustion-derived water vapor, as combustion-derived vapor possesses an unusually negative deuterium excess value (d-excess, d  =  δ2H − 8δ18O). We investigated the relationship between the d-excess of atmospheric vapor, ambient CO2 concentrations, and atmospheric stability across four winters in Salt Lake City, Utah. We found a robust inverse relationship between CO2 excess above background and d-excess on sub-diurnal to seasonal timescales, which was most prominent during periods of strong atmospheric stability that occur during Salt Lake City winter. Using a Keeling-style mixing model approach, and assuming a molar ratio of H2O to CO2 in emissions of 1.5, we estimated the d-excess of combustion-derived vapor in Salt Lake City to be −179 ± 17 ‰, consistent with the upper limit of theoretical estimates. Based on this estimate, we calculate that vapor from fossil fuel combustion often represents 5–10 % of total urban humidity, with a maximum estimate of 16.7 %, consistent with prior estimates for Salt Lake City. Moreover, our analysis highlights that changes in the observed d-excess during periods of high atmospheric stability cannot be explained without a vapor source possessing a strongly negative d-excess value. Further refinements in this humidity apportionment method, most notably empirical validation of the d-excess of combustion vapor or improvements in the estimation of the background d-excess value in the absence of combustion, can yield more certain estimates of the impacts of fossil fuel combustion on urban humidity and meteorology.
  • Keywords:
  • Document Type:
  • Place as Subject:
  • Main Document Checksum:
  • File Type:
  • Supporting Files:
    No Additional Files
No Related Documents.

You May Also Like: