Details:

Journal Title:
Atmospheric Chemistry and Physics
Personal Author:
Rattanavaraha, Weruka ; Chu, Kevin ; Budisulistiorini, Sri Hapsari ; Riva, Matthieu ; Lin, Ying-Hsuan ; ... More +
Rattanavaraha, Weruka ; Chu, Kevin ; Budisulistiorini, Sri Hapsari ; Riva, Matthieu ; Lin, Ying-Hsuan ; Edgerton, Eric S. ; Baumann, Karsten ; Shaw, Stephanie L. ; Guo, Hongyu ; King, Laura ; Weber, Rodney J. ; Neff, Miranda E. ; Stone, Elizabeth A. ; Offenberg, John H. ; Zhang, Zhenfa ; Gold, Avram ; Surratt, Jason D. Less -
NOAA Program & Office:
OAR (Oceanic and Atmospheric Research)
Description:
In the southeastern US, substantial emissions of isoprene from deciduous trees undergo atmospheric oxidation to form secondary organic aerosol (SOA) that contributes to fine particulate matter (PM2.5). Laboratory studies have revealed that anthropogenic pollutants, such as sulfur dioxide (SO2), oxides of nitrogen (NOx), and aerosol acidity, can enhance SOA formation from the hydroxyl radical (OH)-initiated oxidation of isoprene; however, the mechanisms by which specific pollutants enhance isoprene SOA in ambient PM2.5 remain unclear. As one aspect of an investigation to examine how anthropogenic pollutants influence isoprene-derived SOA formation, high-volume PM2.5 filter samples were collected at the Birmingham, Alabama (BHM), ground site during the 2013 Southern Oxidant and Aerosol Study (SOAS). Sample extracts were analyzed by gas chromatography–electron ionization-mass spectrometry (GC/EI-MS) with prior trimethylsilylation and ultra performance liquid chromatography coupled to electrospray ionization high-resolution quadrupole time-of-flight mass spectrometry (UPLC/ESI-HR-QTOFMS) to identify known isoprene SOA tracers. Tracers quantified using both surrogate and authentic standards were compared with collocated gas- and particle-phase data as well as meteorological data provided by the Southeastern Aerosol Research and Characterization (SEARCH) network to assess the impact of anthropogenic pollution on isoprene-derived SOA formation. Results of this study reveal that isoprene-derived SOA tracers contribute a substantial mass fraction of organic matter (OM) ( ∼  7 to  ∼  20 %). Isoprene-derived SOA tracers correlated with sulfate (SO42−) (r2 = 0.34, n = 117) but not with NOx. Moderate correlations between methacrylic acid epoxide and hydroxymethyl-methyl-α-lactone (together abbreviated MAE/HMML)-derived SOA tracers with nitrate radical production (P[NO3]) (r2 = 0.57, n = 40) were observed during nighttime, suggesting a potential role of the NO3 radical in forming this SOA type. However, the nighttime correlation of these tracers with nitrogen dioxide (NO2) (r2 = 0.26, n = 40) was weaker. Ozone (O3) correlated strongly with MAE/HMML-derived tracers (r2 = 0.72, n = 30) and moderately with 2-methyltetrols (r2 = 0.34, n = 15) during daytime only, suggesting that a fraction of SOA formation could occur from isoprene ozonolysis in urban areas. No correlation was observed between aerosol pH and isoprene-derived SOA. Lack of correlation between aerosol acidity and isoprene-derived SOA is consistent with the observation that acidity is not a limiting factor for isoprene SOA formation at the BHM site as aerosols were acidic enough to promote multiphase chemistry of isoprene-derived epoxides throughout the duration of the study. All in all, these results confirm previous studies suggesting that anthropogenic pollutants enhance isoprene-derived SOA formation.
Keywords:
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Air quality
Source:
Atmospheric Chemistry and Physics, 16, 4897–4914
DOI:
https://doi.org/10.5194/acp-16-4897-2016
Document Type:
Journal Article
Funding:
Grant no. NA130AR4310064
Rights Information:
CC BY
Compliance:
Submitted
Main Document Checksum:
[+]
urn:sha256:a08e0ffff0cb69992338f9373d97752fbd81f843d3636c69935f5334f363552c
Download URL:
https://repository.library.noaa.gov/view/noaa/24494/noaa_24494_DS1.pdf
File Type:

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